application of spherical mesoporous silica mcm-41 for adsorption of dibenzothiophene (a sulfur containing compound) from model oil
نویسندگان
چکیده
spherical mesoporous silica mcm-41 was synthesized for adsorptive removal of sulfur compounds from fossil fuels using 1mm solution of dibenzothiophene (dbt) in dodecane as model oil. the prepared silica adsorbent has been characterized by nitrogen adsorption-desorption analysis as well as small angle x-ray scattering (saxs), and transmission and scanning electron microscopy (sem) methods. results showed that the prepared mesoporous adsorbent has ordered pore structures with surface area of 1106 m2/g and mean pore diameter of 3.54 nm. sem micrographs indicated that prepared mesoporous silica (mcm-41) has spherical morphology with the narrow size distribution in the range of 200-300 nm. hexagonal structure of pores has also been confirmed by high resolution transmission electron microscopy and saxs pattern. high performance liquid chromatography analysis has also been utilized to study the kinetics of the dbt adsorption from dodecane solution by means of the synthesized silica. results showed that 0.03 g/ml of mesoporous silica has capability to adsorb more than 42% of dbt (a sulfur containing compound) from dodecane solution. the improvement of mass transfer via adsorption dbt by the prepared nanosorbent is an efficient method for enhancement of biodesulfurization kinetic.
منابع مشابه
Application of Spherical Mesoporous Silica MCM-41 for Adsorption of Dibenzothiophene (A Sulfur Containing Compound) from Model Oil
Spherical mesoporous silica MCM-41 was synthesized for adsorptive removal of sulfur compounds from fossil fuels using 1mM solution of dibenzothiophene (DBT) in dodecane as model oil. The prepared silica adsorbent has been characterized by nitrogen adsorption-desorption analysis as well as Small Angle X-ray Scattering (SAXS), and transmission and Scanning Electron Microscopy (SEM) methods. R...
متن کاملan application of equilibrium model for crude oil tanker ships insurance futures in iran
با توجه به تحریم های بین المملی علیه صنعت بیمه ایران امکان استفاده از بازارهای بین المملی بیمه ای برای نفتکش های ایرانی وجود ندارد. از طرفی از آنجایی که یکی از نوآوری های اخیر استفاده از بازارهای مالی به منظور ریسک های فاجعه آمیز می باشد. از اینرو در این پایان نامه سعی شده است با استفاده از این نوآوری ها با طراحی اوراق اختیارات راهی نو جهت بیمه گردن نفت کش های ایرانی ارائه نمود. از آنجایی که بر...
Tetracycline-Containing MCM-41 Mesoporous Silica Nanoparticles for the Treatment of Escherichia coli.
Tetracycline (TC) is a well-known broad spectrum antibiotic, which is effective against many Gram positive and Gram negative bacteria. Controlled release nanoparticle formulations of TC have been reported, and could be beneficial for application in the treatment of periodontitis and dental bone infections. Furthermore, TC-controlled transcriptional regulation systems (Tet-on and Tet-off) are us...
متن کاملImprovement of Desulfurization Performance of Rhodococcus erythropolis IGTS8 by Assembling Spherical Mesoporous Silica Nanosorbents on the Surface of the Bacterial Cells
MCM-41 mesoporous silica is synthesized based on a self assembly method, using a quaternary ammonium template, CTAB for the adsorption of sulfur compounds from model oil (1.0 mmol/l DBT in dodecane solution). Then the adsorption capability of MCM-41 assembled on the surface of bacterium Rhodococcus erythropolis IGTS8 is examined regarding the improvement of the biodesulfurization process of...
متن کاملAsymmetric Synthesis of Modafinil and its Derivatives by using the Functionalized Silica-based Mesoporous MCM-41
Modafinil [2-[(diphenylmethyl)sulfinyl]acetamide] is used clinically in the treatment of narcolepsy and sleeping disorders. The synthesis of modafinil, begins with the reaction of benzhydrol and thioglycolic acid in trifluoroacetic acid to afford benzhydrylsulfinyl acetic acid. The reaction of acid with thionyl chloride in benzene followed by treatment with ammonium hydroxide gave acetamide...
متن کاملinvestigating the feasibility of a proposed model for geometric design of deployable arch structures
deployable scissor type structures are composed of the so-called scissor-like elements (sles), which are connected to each other at an intermediate point through a pivotal connection and allow them to be folded into a compact bundle for storage or transport. several sles are connected to each other in order to form units with regular polygonal plan views. the sides and radii of the polygons are...
منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
iranian journal of chemistry and chemical engineering (ijcce)ناشر: iranian institute of research and development in chemical industries (irdci)-acecr
ISSN 1021-9986
دوره 33
شماره 3 2014
میزبانی شده توسط پلتفرم ابری doprax.com
copyright © 2015-2023